Silkworm cocoons by cylinders self-assembled from H-shaped alternating polymer brushes
作者:Qiutong Huang, Bo Yang, Huanhuan Liu, Youliang Zhao, and Jianzhong Du* 时间:2014-11-21 点击数:
Abstract:
We report a novel silkworm cocoon-like nanostructure based on the 3D hierarchical self-assembly of cylinders which are spontaneously formed by an H-shaped polymer brush comprising a disulfide-bridged spacer and two brushes with alternating PEG and PCL side chains. Crystalline of PCL between adjacent cylinders bridges cylinders.
文章链接:Polymer Chemistry 2015, 6, 886-890.